Missouri State University

Recent Publications - Nikolay Gerasimchuk

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  1. Ryabchuk, P.; Edwards, A.; Gerasimchuk, N.; Rubina, M.; Rubin, M. "Dual Control of Selectivity in the Synthesis of Homochiral Densely Substituted Cyclopropanes via the Addition of Nucleophiles to in situ Generated Cyclopropenes." Organic Letters. 2013, 15 (23), 6010-6013.
  2. Ramidi, P.; Gerasimchuk, N.; Gartia, Y.; Felton, C.M.; Ghosh, A. "Influence of substituents on the reactivity of cobalt(III) amidoamine complexes for the catalytic synthesis of cyclic carbonate from epoxide and carbon dioxide". Dalton Transactions. 2013, 42, 13151-13160.
  3. Eakins, G.L.; Cooper, M.; Phillips, T.; Gerasimchuk, N.; Breyfogle, B.; Stearman, C.J. "Structural Influences Impacting the Role of the 9-Ylidene Bond in the HOMO-LUMO Tuning of Structures Built upon 9-Fluorenylidene Scaffolds". Can. J. Chem. 2013, 91 (11), 1059-1071.
  4. Gudima, A.O.; Shovkova, G.V.; Trunova, O.K.; Grandjean, F.; Long, G.J.; Gerasimchuk, N. "Sodium-Centered Dodecanuclear Co(II) and Ni(II) Complexes with 2-(Phosphono methylamino)succinic Acid: Studies of Spectroscopic, Structural, and Magnetic Properties." Inorganic Chemistry. 2013, 52 (13), p. 7467-7477.
  5. Cheadle, C.; Gerasimchuk, N.; Barnes, C.L.; Tyukhtenko, S.I.; Silchenko, S. "First bis- cyanoxime: synthesis and properties of a new versatile and accessible polydentate bifunctional building block for coordination and supramolecular chemistry" Dalton Transactions. 2013, 42 (14), p. 4931 – 4946.
  6. Hilton, M.; Gerasimchuk, N.; Silchenko, S.; Charlier, H. , "Synthesis, Properties and Crystal Structure of the 2,4-dichlorophenyl-cyanoxime - a powerful carbonyl reductase inhibitor." J. Chem. Crystallography. 2013, 43 (3), p.157-164.
  7. Curtis, S.; Ilkun, O.; Brown, A.; Silchenko, S.; Gerasimchuk, N. "Synthesis, spectroscopic and structural characterization of the first phenyl bis-cyanoximes: non-chelating extended ionisable building block ligands for new MOFs." Cryst. Eng. Comm. 2013, 15, p.152-159.

  8. D. Marcano, N. Gerasimchuk, V. Nemykin, and S. Silchenko.  “Synthesis, Characterization and Studies of Coordination Polymers With Isomeric  Pyridylcyanoximes: Route to Metal Ribbons With Very Short Tl---Tl separations.” Cryst. Growth Des., 2012, 12, 2877-2889.

  9. Ratcliff, Jessica, Paul Durham,, Michael Keck, Andriy Mokhir, and Nikolay Gerasimchuk, "Part 2: In Vitro Cytotoxicity Studies of Two ML2 Complexes (M = Pd, Pt; L = 2-cyano-2-isonitroso-N-morpholylacetamide, HMCO," Inorganica Chimica Acta, 2012, 385, 11-20.
  10. Ratcliff, Jessica, Janina Kuduk-Jaworska, Henryk Chojnacki, Victor Nemykin, and Nikolay Gerasimchuk, "Part 1: Experimental and Theoretical Studies of 2-cyano-2-isonitroso-N-piperidynylacetamide (HPiPCO), 2-cyano-2-isonitroso-N-morpholylacetamide (HMCO) and Their Pt- and Pd-complexes," Inorganica Chimica Acta, 2012, 385, 1-10.
  11. Solntsev, P.V., B. D. Neisen; J. R. Sabin, N. N. Gerasimchuk, V. N. Nemykin, “Synthesis, characterization, X-ray structure, and mixed-valence states of trans-dichlorotin(IV)-5,10,15,20-tetraferrocenylporphyrin,” J. Porphyrins & Phthalocyanines, 2011, 15: 612–621.
  12. Gerasimchuk, N. “An Excursion into the Intriguing World of Polymeric Tl(I) and Ag(I) Cyanoximates,” Polymers, 2011, 3, 2-37; doi:10.3390/polym30x000x.
  13. Albright, A., D.Eddings, R. Black, C. J. Welch, N. N. Gerasimchuk, R. E. Gawley, “Design and Synthesis of C2-Symmetric N-Heterocyclic Carbene Precursors and Metal Carbenoids,” Journal of Organic Chemistry, 2011, 76, 7341–7351.
  14. Gerasimchuk, N. “Synthesis, Characterization and Remarkable Applications of Light-insensitive Silver(I) Cyanoximates,” in New Trends in Coordination, Bioinorganic, and Applied Inorganic Chemistry, p.106-113;M. Melník, P. Segľa, and M. Tatarko (Eds.),Slovak University of Technology Press, 2011; ISBN 978-80-227-3509-4.
  15. Beckford, F., D. Dourth, M. Shaloski, J. Didion, J. Thessing, J. Woods, V. Crowell , N. Gerasimchuk, A. Gonzalez-Sarriasc and N. P. Seeramc, “Half-sandwich Ruthenium–arene Complexes with Thiosemicarbazones: Synthesis and Biological Evaluation of [(η6-p-cymene)Ru(piperonal thiosemicarbazones)Cl]Cl Complexes,” Journal of Inorganic Biochemisty, 105, 2011, 1019-1029.
  16. Beckford, F.,  J. Thessing, J. Woods, J. Didion, N. Gerasimchuk, A. Gonzalez-Sarriasc and N. P. Seeramc, “Synthesis and Structure of [(g6-p-cymene)Ru(2-anthracen-9-ylmethylene-N-ethylhydrazinecarbothioamide)Cl]Cl; Biological Evaluation, Topoisomerase II Inhibition and Reaction With DNA and Human Serum Albumin," Metallomics, 2011, 3, 491-502.
  17. Filatov, A. S., O. Hietsoi, Y. Sevrygina, N. N. Gerasimchuk, and M. A. Petruhina, “Reversible Cu4 à Cu6 Core Interconverison and Temperature Induced Single-Crystal-to-Single-Crystal Phase Transition for Copper(I) Carboxylate,” Inorganic Chemistry, 2010, 49 (4), p.1626-1633.
  18. Gerasimchuk, N., C. L. Barnes,  and D. Boaz, “Preparation, Spectroscopic and Structural Characterization of the First Co(III) Cyanoxime Complex:  Two Polymorphs of fac-, tris-(benzoylcyanoximato)cobalt(III), Co(BCO)3.” Journal of Coordination Chemistry, 2010, 63 (6), p.943.
  19. US Patent #7,727,967 B2  “Cyanxome Inhibitors of Carbonic Reductase and Methods of Using Said Inhibitors In Treatments Involving Antracyclines”.
  20. Gerasimchuk, N., A. N. Esaulenko, K. N. Dalley and C. Moore, “2-Cyano-2-isonitroso  Acetamide and its Ag(I) Complexes. Silver(I) Cyanoximate as a Non-electric Gas Sensor," Dalton Transactions, 2010, 39, p.749-764.

  21. Glover, Garrett, Nikolay Gerasimchuk, Richard Biagioni, and Konstantin V. Domasevitch, "Monovalent K, Cs, Tl, and Ag Nitrosodicyanomethanides:  Completely Different 3D Networks with Useful Properties of Luminescent Materials and Nonelectric Sensors for Gases," Inorg. Chem. 2009, 48 (6), 2371-2382, DOI: 10.1021/ic801364w.

  22. Glover, G., N. Gerasimchuk and K. V. Domasevitch, "Monovalent K, Cs, Tl and Ag Nitrosodicyanmethanides: Completely  Different 3D Networks With Useful Properties," Inorganic Chemistry, 2008, manuscript # ic-2208-1364w.R1.
  23. Ilkun,Olesya T., Stephen J. Archibald, Charles L. Barnes, Nikolay Gerasimchuk, Richard Biagioni, Svitlana Silchenko, Olga A. Gerasimchuke and Victor N. Nemykin, "Benz(2-heteroaryl)cyanoximes and their Tl(I) complexes: New Room Temperature Blue Emitters," The Royal Society of Chemistry, Dalton Trans., 2008, 5715–5729.
  24. Owen, Travis, Fernande Grandjean, Gary J. Long, Konstantin V. Domasevitch, and Nikolay Gerasimchuk, "Synthesis and Characterization of Two Intensely Colored Tris(benzoylcyanoxime)iron(II) Anionic Complexes," Inorg. Chem., 2008, 47, 8704-8713.
  25. Goeden, Leon, Nikolay Gerasimchuk, Paul Durham, Charles Barnes, John F. Cannon, Svitlana Silchenko, and Ismael Hidalgo, "Synthesis and Characterization of Disubstituted Arylcyanoximes and Their Several Metal Complexes,” Inorganica Chimica Acta, 2008, 361, 1983-2001.
  26. Patent application #11776536, priority date: July 11th, 2007: “Cyanoxime Inhibitors of Carbonyl Reductase and Methods of Using Said Inhibitors in Treatments Involving Antracyclines;” inventors: Henry A. Charlier, Jr., Boise State University, and Nikolay Gerasimchuk. Missouri State University.
  27. Gerasimchuk, N. N., T. Maher, P. Durham, K. V. Domasevitch, J. Wilking and A. Mokhir, "Tin(IV) Cyanoximates: Synthesis, Characterization, and Cytotoxicity," Inorganic Chemistry, 2007, 46, No. 18, pp 7268-7284.
  28. Robertson, D. R.; Cannon, J. F.; Gerasimchuk, N. N. "Double-Stranded Metal-Organic Networks for One dimensional Mixed Valence Coordination Polymers," Inorganic Chemistry, 2005, 44, No. 22.
  29. Magda, D. J.; Gerasimchuk, N.; Wang, Z.; Sessler, J. L.; Miller, R. A. "Mechanistic Studies of Motexafin Gadolinium (Xcytrin®):  A Redox Active Agent that Reacts with Electron-rich Biological Substrates," American Chemical Society Symposium Series no. 903, Chapter 8. American Chemical Society, Washington, DC; 2005.
  30. Gerasimchuk, N. and N. Kent Dalley, "Demetallation of a Ni(II) Tetraazamacrocyclic Complex by Cyanoxime Resulting in the Formation of a Stereospecific Trinuclear Compound [Na(H2O)6]+[NaNi2L6]¯ (L = NC–C(NO)–C(O)NH2¯ )", J. Coord. Chem., November 2004, 57, No. 16, pp 1431-1445.
  31. Robertson, D., C. Barnes and N. Gerasimchuk, "Synthesis of the Monosubstituted Arylcyanoxime and Its Na, TI(I) and Ag(I) Compounds," J. Coord. Chem., September 2004, 57, 1205-1216.
  32. Eddings, D., C. Barnes, N. Gerasimchuk, P. Durham, K. Domasevich, "First Bivalent Palladium and Platinum Cyanoximates: Synthesis, Characterization and Biological Activity," Inorg. Chem., 2004, 43, No. 13, p.3894-3909.
  33. Magda, D., Z. Wang, N. Gerasimchuk, W. Wenhao, P. Anzenbacher, J. Sessler, "Synthesis of Texaphyrin Conjugates," Pure and Appl. Chem., 2004, 76, No 2, pp.365-374.
  34. Magda, D. J., Z. Wang, N. N. Gerasimchuk, W. Wei, P. Anzenbacher, Jr., and J. L. Sessler, "Synthesis of Rexaphyrins Conjugates," Pure and Applied Chemistry, 2003, October issue.
  35. Magda, D., N. N. Gerasimchuk, P. Lecane, R. A. Miller, J. E. Biaglow, J. L. Sessler, "Motexafin Gadolinium Reacts with Ascorbate to Produce Reactive Oxygen Species," Chemical Communications, 2002, December issue.
  36. Hannah, S., V. Lynch, D. M. Guldi, N. N. Gerasimchuk, C. B. MacDonald, D. Magda, J. L. Sessler, "Late First-Row Transition-Metal Complexes of Texaphyrin," Journal of the American Chemical Society, 2002, 124, No. 28, 8416-8427.
  37. Magda, D., C. Lepp, N. N. Gerasimchuk, I. Lee, J. L. Sessler, A. Lin, J. E. Biaglow, R. A. Miller, "Redox Cycling by Motexafin Gadolinium Enhances Cellular Response to Ionizing Radiation by Forming Reactive Oxygen Species," International Journal Oncology, Biology and Physics, 2001, 51, No. 4, 1025-1036.
  38. Hannah, S., V. M. Lynch, N. N. Gerasimchuk, D. Magda, J. L. Sessler. - Synthesis of a Metal-Free Texaphyrin," Organic Letters, 2001, 3, No. 24, 3911-3914.
  39. Shimanovich, R., S. Hannah, V. Lynch, N. N. Gerasimchuk, T. D. Mody, D. Magda, J. L. Sessler, J. T. Groves, "Mn(II)-Texaphyrin as a Catalyst for the Decomposition of Peroxynitrite," Journal of the American Chemical Society, 2001, 123, p.3613-3614.
  40. Domasevitch, K. V.,  N. N. Gerasimchuk, A. A. Mokhir - Organoantimony(V) cyanoximates: Synthesis, Spectra and Crystal Structures. Inorganic Chemistry, 2000, 39, No6, p.1227-1237.
  41. Guildi, D. M., T. D. Mody, N. N. Gerasimchuk, D. Magda, J.L. Sessler - Influence of Large Metal Cations on the Photophysical Properties of Texaphyrin, a Rigid Aromatic Chromophore. Journal of the American Chemical Society, 2000, 122, p.8289-8298.